Scientist have found out that under very high pressure not only the valiance electron can bond but the inner electrons can bond too. When Fluorine was put under very high pressure along with Cesium not only the outer most electrons started to bond but the inner ones started to bond too. It breaks the rule that states that inner electrons cannot react. They can react and as science advances i believe that we can maybe even be able to see the exact location of an electron if we had the right equipment.
http://www.scientificamerican.com/article.cfm?id=chemical-bonds-inner-shell-electrons
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